Microcrystalline Waxes: Macro-Flexibility

Microcrystalline Waxes are products derived from petroleum, consisting of complex hydrocarbon mixtures that include normal paraffin, as well as of monocyclic and polycyclic compounds, which are products with a ramified molecular structure. Microcrystalline Waxes have a very high average molecular weight (580-700), with a chain length between 40 and 50 carbon atoms, resulting in a high viscosity, considerably higher than that observed in Paraffin Waxes.

Unlike Paraffin Waxes, which are formed by macro-crystals, Microcrystalline Waxes are formed by very small and flexible crystals, which results in a higher oil affinity (oil gets literally “trapped” inside the microcrystalline structure and is not able to migrate to the surface). Due to these distinctive properties, Microcrystalline Waxes are highly malleable and less fragile than Paraffin Waxes.

Microcrystalline Waxes are compatible with most vegetable, animal and mineral waxes, as well as with a great variety of synthetic and natural resins. Their properties make them an essential raw material for a wide range of applications including cosmetics, chewing gum, paper, cardboard, industrial coatings, candles, anticorrosive coatings, adhesives and textile products, among others.

Properties of Microcrystalline Waxes

Code

Product

Melting Point

Penetration

Color

2001

Microcrystalline Wax

178-189

15-20

1.5-2.5

2002

Amber Wax

172-183

15 max.

7.0 max.

2003

Yellow Slack

147-160

30-50

5.0 max.

2005

Amber Petrolatum 158

122 min

60 min

7.5 max.

2014

Modeling Clay Base Wax

153-171

90-125

4.5 max.

2015

Modeling Clay Wax

153-171

90-125

4.5 max.

2017

Microcrystalline Wax

162-172

-

2.0 max.

2022

White Microcrystalline Wax

154-165

16-33

+8 min.

2024

Mulprox 2024

176-189

10-25

0.5 max.

2031

Mulprox 2031

144-162

18-30

4.5 max.

2033

Microcrystalline Wax

172-187

16 max.

3.0 max.

2036

Nozono Wax 29-32

158-169

20 max.

2.0 max.

2037

Nozono Wax 31-33

154-165

20 max.

1.5 max.

2038

Nozono Wax A

156-176

20 max.

4.0 max.

2055

Cream Paraffin

135-153

35-45

2.0 max.

2063

Gasket Wax 0-202

153 min

65-75

4.5 max.

2065

Crayon Wax

144-158

30-45

3.5 max.

2075

Campeche Wax

172-180

20-35

7.0 max.

2085

Wick Wax

154-181

15 max.

1.0 max.

Notes:
Melting Point (ºF) by ASTM D127 method [figures in red, Congealing Point (ºF) by ASTM D938]. Penetration (dmm) ASTM D1321. Color ASTM D1500 (figures in green, ASTM D156).


Comparison between Paraffin Waxes and Microcrystalline Waxes

Paraffin Waxes

Microcrystalline Waxes

They consist of linear-saturated compounds

They have a higher percentage of ramified and cyclic structures

Their carbon number is around 18-40

Their carbon number is around 40-50

Their molecular weight is around 360-420

Their molecular weight is around 580-700

Their melting point is 115-154 ºF

Their melting point is 149-189 °F

They present a bright appearance

They present an opaque appearance

They fracture under cut conditions

They are resistant to fractures

All paraffin grades break under compression

They are plastic and tend to flow under compression

They do not have capacity to hold oil in their structure

They have capacity to hold oil in their structure, getting softer and plastic

They are transparent when forming films

They are opaque when forming films

They fracture when applied in the film form

They do not fracture when forming films

They contract significantly when solidifying

They contract slightly when solidifying

Their average viscosity is around 30-45 SUS at 212 ºF

Their average viscosity is around 55-100 SUS at 212 ºF

 

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